Aerosol-assisted CVD of cadmium diselenoimidodiphosphinate and formation of a newiPr2N2P3 + ion supported by combined DFT and mass spectrometric studies

dc.contributor.author	Oyetunde, Temidayo
dc.date.accessioned	2022-02-08T10:48:59Z
dc.date.available	2022-02-08T10:48:59Z
dc.date.issued	2016-10-25
dc.description	Depositon of cadmium selenide together with an aromatic ion from cadmium diselenide complex.	en_US
dc.description.abstract	Aerosol-assisted chemical vapour deposition (AACVD) of Cd[(SePiPr2)2N]2 is shown to deposit cadmium selenide and/or cadmium phosphide on glass substrates, depending upon the growth conditions. The phase, structure, morphology and composition of the films were characterised by X-ray powder diffraction (XRD), scanning electron microscopy, energy dispersive X-ray analysis and X-ray photoelectron spectroscopy. The XRD indicated a hexagonal phase for cadmium selenide, whilst cadmium phosphide was monoclinic. Pyrolysis gas chromatography-mass spectrometry and density functional theory were used to deduce a breakdown mechanism for the deposition that favoured the formation of a new aromatic iPr2N2P3+ ion.	en_US
dc.identifier.uri	http://dspace.run.edu.ng:8080/jspui/handle/123456789/1083
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry (RSC)	en_US
dc.subject	Chalcogenides	en_US
dc.subject	Single-Source Precursors	en_US
dc.subject	Cadmium Selenide	en_US
dc.subject	AACVD	en_US
dc.subject	DFT	en_US
dc.subject	XRD	en_US
dc.title	Aerosol-assisted CVD of cadmium diselenoimidodiphosphinate and formation of a newiPr2N2P3 + ion supported by combined DFT and mass spectrometric studies	en_US
dc.type	Article	en_US

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Description:: Deposition of cadmium selenide and an aromatic ion from cadmium diselenide precursor

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