The Effect of some Operating Variables in the Adsorption of Lead and Cadmium ions unto Modified Kaolin Clay
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Date
2005-12-15
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Elsevier: Journal of Hazardous Materials
Abstract
Modification of kaolinite clay mineral with orthophosphate (p-modified sample) enhanced adsorption of Pb and Cd ions from aqueous solutions of the metal ions. Increasing pH of solutions of metal ions, increasing adsorbent dose and increasing concentration of metal ion, increased the adsorption of metal ions. Adsorption of both metal ions simultaneously on both unmodified and p-modified samples indicates that adsorption of
one metal ion is suppressed to some degree by the other. The presence of electrolyte and their increasing concentration reduced the adsorption capacities of both unmodified and p-modified samples
for the metal ions. Ca-electrolytes had more negative effect on the adsorption capacities of the adsorbents than Na-electrolytes. Ca-electrolytes reduced adsorption capacities of the adsorbents for Pb and Cd ions. From Langmuir plots it was observed that these electrolytes increased the binding energy constant of the metal ions unto the adsorbents especially on the p-modified samples. The rate of adsorption of Pb and Cd ions on p-modified adsorbent were increased and equilibrium of metal ion solution were more quickly
reached (8 min for Pb ions and 12 min for Cd ions) with p-modified adsorbent as against 20 min for adsorption of both metal ions on unmodified adsorbent when 200 mg/L of metal ion solutions were used during the kinetic studies. When adsorption data were fitted against Langmuir, Freundlich, Toth and Langmuir–Freundlich isotherms, satisfactory fits were found with the Freundlich isotherm. However, at low concentration of metal ions, data also showed satisfactory fits to Langmuir isotherm.
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Keywords
Adsorption, Kaolinite clay, p-Modified, Adsorption capacities