A Measurement of Selected Polycyclic Aromatic Hydrocarbons in Petroleum Product Contaminated Soils Using a Gas Chromatograph
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Date
2015
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Publisher
Taylor & Francis
Abstract
Oil contaminated soils around refined petroleum products depot and retailing stations were investigated for selected polycyclic aromatic hydrocarbons (PAHs) to determine their levels in the soils. Soil samples were collected using standard analytical procedures and the petroleum hydrocarbons extracted using standard
method, while the PAHs (benzo[a]pyrene, benz[a]anthracene, chrysene, benzo[b]fluoranthene, and anthracene) contents of the extracted petroleum hydrocarbons were determined using SNR 8126 gas chromatograph equipped with a flame ionization detector (FID). The results indicated that benz[a]anthracene
has the highest concentrations in both the oil depot contaminated soils (59.1 ± 3.3 mg/kg) and oil
retailing station contaminated soils (20.8 ± 2.1 mg/kg). The results also showed that the oil depot contaminated
soils were burdened with the analyzed PAHs than oil retailing station contaminated soils; this was confirmed by the results of t test analysis. Comparison of the values of the PAHs in the oil impacted soils with their background levels showed that their values in the two sets of oil impacted soils were excessive; this was corroborated with their high pollution (PI) and geoaccumulation (Igeo) index values, except chrysene, which moderately polluted the soils (low PI and Igeo values); this was clear indication of indiscriminate discharge of petroleum fuels and petrochemicals into the soils.
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Keywords
GC, oil depot, oil retailing station, petroleum, soil contamination, PAH