Phenyl Substituted ditelluro-imidodiphosphinate complexes of iron, nickel, palladium and platinum, and their pyrolysis Studies Generating metal tellurides

dc.contributor.author	Oyetunde, Temidayo
dc.date.accessioned	2022-02-08T10:46:49Z
dc.date.available	2022-02-08T10:46:49Z
dc.date.issued	2019-01-10
dc.description	Deposition of Metal tellurides from tellurium complexes of transition metals.	en_US
dc.description.abstract	The tellurium complexes M[N(PPh2Te)2]n (M = Fe (1), Ni (2), Pd (3), Pt (4) and n = 2 or 3) have been prepared using the ditellurido anions [N(PPh2Te)2] and their ability to generate tellurides was investigated by pyrolysis in a quartz glass tube, under vacuum at 500 C for 90 min. The products were characterised by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis of Xrays (EDAX) and X-ray photoelectron spectroscopy (XPS). The XRD revealed an orthorhombic phase for the metal telluride from 1, while the hexagonal phase was observed for tellurides from 2, 3 and 4 respectively. Magnetic measurements on FeTe2 (from 1) indicated an antiferromagnetic sample with a transition temperature at 75 K.	en_US
dc.identifier.uri	http://dspace.run.edu.ng:8080/jspui/handle/123456789/1080
dc.language.iso	en	en_US
dc.publisher	Elsevier	en_US
dc.subject	Metal Tellurides	en_US
dc.subject	Pyrolysis	en_US
dc.subject	Antiferromagnetic	en_US
dc.subject	Imidodiphsosphinate ligands	en_US
dc.subject	Single-Source Precursors	en_US
dc.subject	XPS	en_US
dc.title	Phenyl Substituted ditelluro-imidodiphosphinate complexes of iron, nickel, palladium and platinum, and their pyrolysis Studies Generating metal tellurides	en_US
dc.type	Article	en_US

Now showing 1 - 1 of 1

Name:: Polyhedron Paper.pdf
Size:: 867.38 KB
Format:: Adobe Portable Document Format
Description:: Synthesis of metal tellurides from the pyrolysis of transition metal tellurium complexes

Now showing 1 - 1 of 1