Solventless Migratory-Insertion Reactions of Substituted Cyclopentadienyl Iron Complexes Induced by Electron Donor Ligands
| dc.contributor.author | Adeyemi, Olalere | |
| dc.date.accessioned | 2022-02-08T09:55:15Z | |
| dc.date.available | 2022-02-08T09:55:15Z | |
| dc.date.issued | 2009-07-02 | |
| dc.description.abstract | Reaction between solid (C5H5)Fe(CO)2CH3 and a range of solid phosphine ligands, L (L = PPh3, P(m-CH3C6H4)3, P(p-CH3C6H4)3, P(p-FC6H4)3, P(p-ClC6H4)3, PCy3) occurred in the absence of solvent in the melt phase to give the migratory-insertion products, (C5H5)Fe(CO)(COCH3)(L). The reaction was more rapid with small electron withdrawing ligands. Insertion reaction between (RC5H4)Fe(CO)2R’ (R = H, CH3; R’ = CH3, CH2Ph) and gaseous ligands such as SO2 and CO were also studied. The insertion of SO2 occurred readily for all the substrates investigated, but CO insertion did not occur (< 1 %) using the solventless reaction condition. | en_US |
| dc.identifier.uri | http://dspace.run.edu.ng:8080/jspui/handle/123456789/1065 | |
| dc.language.iso | en | en_US |
| dc.subject | Melt phase | en_US |
| dc.subject | Solventless chemistry | en_US |
| dc.subject | Iron complexes | en_US |
| dc.subject | Cyclopentadiene | en_US |
| dc.subject | Migratory-insertion | en_US |
| dc.title | Solventless Migratory-Insertion Reactions of Substituted Cyclopentadienyl Iron Complexes Induced by Electron Donor Ligands | en_US |
| dc.type | Article | en_US |