The Solid-state Isomerization of cis and trans-(η5 -C5H4Me)Mo(CO)2(P(Oi Pr)3)I
| dc.contributor.author | Adeyemi, Olalere | |
| dc.date.accessioned | 2022-02-08T10:00:49Z | |
| dc.date.available | 2022-02-08T10:00:49Z | |
| dc.date.issued | 2002-06-16 | |
| dc.description.abstract | The cis- and trans-(η5 -C5H4Me)Mo(CO)2(P(Oi Pr)3)I complexes undergo a bi-directional thermal ligand isomerization reaction to yield an equilibrium mixture of isomers (30/70 cis/trans ratio, 90 °C, < 80 min) in the solid state. The activation energy barrier for the cis-trans isomerization reaction (80–100 °C) was found to be 68 ± 10 kJ mol–1. In benzene (reflux, 2 h) this isomer ratio was found to be 70:30 cis/trans. DSC and powder XRD studies have revealed reactions that occur in the solid state entailing decomposition and isomerization. DSC experiments did not reveal the presence of the cis–trans isomerization reaction. | en_US |
| dc.identifier.uri | http://dspace.run.edu.ng:8080/jspui/handle/123456789/1067 | |
| dc.language.iso | en | en_US |
| dc.subject | Isomerization/ solid state / XRD powder diffraction / molybdenum | en_US |
| dc.title | The Solid-state Isomerization of cis and trans-(η5 -C5H4Me)Mo(CO)2(P(Oi Pr)3)I | en_US |
| dc.type | Article | en_US |