The deposition of cadmium selenide and cadmium phosphide thin films from cadmium thioselenoimidodiphosphinate by AACVD and the formation of an aromatic species†

Simple item page
dc.contributor.authorOyetunde, Temidayo
dc.date.accessioned2022-02-08T10:47:32Z
dc.date.available2022-02-08T10:47:32Z
dc.date.issued2019-01-10
dc.descriptionDeposition of cadmium selenide and cadmium phsphide from the AACVD of cadmium thioselenoimidodiphosphinate complex...en_US
dc.description.abstractAerosol-assisted chemical vapour deposition (AACVD) of Cd[(SPiPr2)(SePiPr2)N]2 yields hexagonal cadmium selenide and monoclinic cadmium phosphide films on glass substrates between 475 and 525 °C at different argon flow rates. The films were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis of X-rays (EDAX) and X-ray photoelectron spectroscopy (XPS). All the results of XRD, EDAX and XPS are in agreement with our previous investigations on Cd[(SePiPr2)2N]2. A breakdown mechanism is proposed based on mass spectra and density functional theory calculations. A large peak at m/z 207 in the mass spectra, previously assigned by us as a new aromatic species, is also observed for this complex.en_US
dc.identifier.urihttp://dspace.run.edu.ng:8080/jspui/handle/123456789/1081
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistry (RSC)en_US
dc.subjectChalcogenidesen_US
dc.subjectSingle-Source Precursorsen_US
dc.subjectCadmium Phosphideen_US
dc.subjectAACVDen_US
dc.subjectCadmium Selenideen_US
dc.subjectAromatic Ionen_US
dc.subjectCadmium thioselenoen_US
dc.titleThe deposition of cadmium selenide and cadmium phosphide thin films from cadmium thioselenoimidodiphosphinate by AACVD and the formation of an aromatic species†en_US
dc.typeArticleen_US
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
CdSSe Dalton Trans paper.pdf
Size:
1.02 MB
Format:
Adobe Portable Document Format
Description:
Deposition of cadmium selenide and cadmium phosphide from cadmium thioselenoimidodiphosphinate precursor.
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Department of Chemical Sciences